Little is known about the mid-infrared (MIR) polarization at high-angular resolution of Active Galactic Nuclei (AGN), however, the polarimetric mode of CanariCam on the 10.4-m Gran Telescopio CANARIAS has opened a new window to reveal its core. We have found a variety of results: 1) A Highly polarized synchrotron emission in the core of Cygnus A; 2) a very complex MIR polarization structures in and around the core of NGC 1068; and 3) a very low polarized core of Mrk 231. In this talk, I will present new CanariCam polarimetric results on several AGN which provide key information on our understanding of the AGN structure and jet formation.