Photolytic Decomposition of Hydrogenated C70: C70H38 and C70D38
The hydrogenated C70 fullerenes C70H38 and C70D38 have been photolyzed at 245nm under Ar or He flow. The photolysis rate constant have been measured: k = 1.54x10-3s-1 for C70H38, and the photolysis of C70D38 occurs at a rate of 1.17x10-3s-1. A remarkable isotope effect in the photolysis of the two molecules has been determined kH/kD = 1.32. The
Manchado, A. et al.
Fecha de publicación:
3
2009
Número de citas
0