The spectral signatures of optical absorbers, when combined with those of infrared molecules, play a critical role in constraining the cloud properties of exoplanet atmospheres. We aim to use optical transmission spectroscopy to confirm the tentative color signature previously observed by multiband photometry in the atmosphere of hot Jupiter HAT-P-55b. We observed a transit of the HAT-P-55b with the OSIRIS spectrograph on the Gran Telescopio Canarias (GTC). We created two sets of spectroscopic light curves, using the conventional band-integrated method and the newly proposed pixel-based method, to derive the transmission spectrum. We performed Bayesian spectral retrieval analyses on the transmission spectrum to interpret the observed atmospheric properties. The transmission spectra derived from the two methods are consistent, both spectrally resolving the tentative color signature observed by MuSCAT2. The retrievals on the combined OSIRIS and MuSCAT2 transmission spectrum yield a detection of Na at 5.5σ and a tentative detection of MgH at 3.4σ. The current optical-only wavelength coverage cannot constrain the absolute abundances of the atmospheric species. Space-based observations covering the molecular infrared bands or ground-based high-resolution spectroscopy are needed to further constrain the atmospheric properties of HAT-P-55b.