As a high-resolution, near-infrared, fiber-fed instrument, APOGEE presents a unique opportunity to obtain multi-epoch radial velocity measurements of a large number of low-mass stars. These observations will reveal unseen companions, improving our understanding of stellar multiplicity at the bottom of the Main Sequence, and may even identify candidate sub-stellar companions. These same data contains an unprecedented wealth of information about the kinematics, rotation, and metallicities of these stars. I will describe the status of our Ancillary Science program, and ongoing efforts to get the best possible radial velocity precision from the APOGEE data.