Phase-transfer catalysis in the oxidation of C60 and C70 fullerene with KMnO4 and crown ether

Bibcode
2018FNCN...26..578C
DOI
10.1080/1536383X.2018.1474348
Cataldo, F.; García-Hernández, D. A.; Manchado, A.
Bibliographical reference

Fullerenes, Nanotubes and Carbon Nanostructures, vol. 26, issue 9, pp. 578-583

Advertised on:
9
2018
Number of authors
3
IAC number of authors
2
Citations
1
Refereed citations
1
Description
The KMnO4 oxidation reaction of C60 or C70 fullerenes in benzene solution proceeds smoothly and almost quantitatively in presence of the crown ether 18-crown-6 as phase-transfer agent. The oxidation reaction was followed spectrophotometrically from the early stages to the completion. Essentially fullerenols or polyhydroxylated fullerenes were produced as confirmed also by FT-IR spectroscopy. The resulting degree of hydroxylation of both C60 and C70 was determined as C60(OH)28 and C70(OH)26. As secondary structures, also epoxide and carboxylic groups were detected.
Related projects
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Nucleosynthesis and molecular processes in the late stages of Stellar Evolution
Low- to intermediate-mass (M < 8 solar masses, Ms) stars represent the majority of stars in the Cosmos. They finish their lives on the Asymptotic Giant Branch (AGB) - just before they form planetary nebulae (PNe) - where they experience complex nucleosynthetic and molecular processes. AGB stars are important contributors to the enrichment of the
Domingo Aníbal
García Hernández
In progress
Type
Refereed
Exoplanetary Systems & Solar System (SEYSS)
Stellar & Interstellar Physics (FEEI)
The Milky Way and the Local Group (MWLG)

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